Synthesis and characterization of organogel from poly(acrylic acid) with cellulose acetate

AudienciaPúblico en generales_ES
CoberturaMéxicoes_ES
Fecha de ingreso2026-09-15T00:30:25Z
Fecha de publicación2010-01-01
ResumenAbstract In the last decade, the interest in physical organogels has grown rapidly with the discovery and synthesis of a very large number of diverse molecules, which used organic solvents at low concentrations. New organogels based on poly (acrylic acid) (PAA) and cellulose acetate (CA) were prepared as thin films to study properties and swelling behavior. In organogels synthesis different crosslinking agent and initiator concentrations were studied. The swelling for PAA/CA organogels was carried out with acetone at 3 different temperatures (30°, 40° and 50 °C) and pH of 6.5 (pH acetone = 6.5). The higher swelling for PAA/CA organogels was 770% for 25PAA/75CA composition ratio with 3%wt N,N´-methylene-bis acrylamide (MBA) and 1%wt potassium persulphate (KPS) at 30 °C. The films were analyzed by FTIR and the presence of functional groups of each polymer was confirmed without secondary reactions. The DSC analysis indicated two glass transition temperatures (T g ); at 106 °C corresponding to PAA and 86 °C, corresponding to CA, respectively, indicative of phase separation, characteristic of gels. Surface morphology was analyzed by Scanning electron microscopy (SEM) showing smooth surface and small crystal forms.es_ES
Doihttps://doi.org/10.1515/epoly.2010.10.1.1613es_ES
URIhttps://riuat.uat.edu.mx/handle/123456789/2361
Idiomaeses_ES
EditorialWalter de Gruyter GmbHes_ES
Relacióne-Polymerses_ES
URL relacionadohttps://doi.org/10.1515/epoly.2010.10.1.1613es_ES
DerechosAcceso abierto (Metadatos de producción científica)es_ES
Licenciahttp://purl.org/coar/access_right/c_abf2es_ES
Fuentee-Polymers
TítuloSynthesis and characterization of organogel from poly(acrylic acid) with cellulose acetatees_ES
TipoArtículoes_ES
ArbitradoHa sido Arbitradoes_ES
AutorRivas-Orta, Valeria
AutorAntonio-Cruz, Rocío
AutorRivera-Armenta, José Luis
AutorMendoza-Martínez, Ana
AutorRamírez-Mesa, Roberto
AutorRivas-Orta, Valeriaes_ES
AutorAntonio-Cruz, Rocíoes_ES
AutorRivera-Armenta, José Luises_ES
AutorMendoza-Martínez, Anaes_ES
AutorRamírez-Mesa, Robertoes_ES
InstituciónUniversidad Autónoma de Tamaulipas
InstituciónUniversidad Autónoma de Tamaulipases_ES
Número1es_ES
URL relacionadahttps://doi.org/10.1515/epoly.2010.10.1.1613
Tipo de artículoIndexado
Tipo de artículoIndexadoes_ES
Volumen10es_ES

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