A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand {[}C5H4N-2-CH3C=N-(CH2) 3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings

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AudienciaPúblico en generales_ES
CoberturaMéxicoes_ES
Fecha de ingreso2026-10-05T16:33:18Z
Fecha de publicación2015-01-01
ResumenThe facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N-1-(1-(pyridin-2-yl) ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species {[}Pd(L1) Cl]{[}BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a kappa(3)-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks. (C) 2015 Elsevier B.V. All rights reserved.es_ES
Doihttps://doi.org/10.1016/j.jorganchem.2015.08.024es_ES
URIhttps://riuat.uat.edu.mx/handle/123456789/5109
Idiomaenes_ES
EditorialELSEVIER SCIENCE SAes_ES
RelaciónJournal of Organometallic Chemistryes_ES
URL relacionadohttps://doi.org/10.1016/j.jorganchem.2015.08.024es_ES
DerechosAcceso restringido / Suscripción (Metadatos de producción científica)es_ES
Licenciahttp://purl.org/coar/access_right/c_16eces_ES
FuenteJournal of Organometallic Chemistry
Palabra clavePalladium complexeses_ES
Palabra clavePyridyl imine ligandses_ES
Palabra claveCrystal structureses_ES
Palabra claveSuzuki-Miyaura couplingses_ES
Palabra claveCatalysises_ES
Palabra claveNon-covalent interactionses_ES
Palabra claveSchiff base compoundses_ES
TítuloA simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand {[}C5H4N-2-CH3C=N-(CH2) 3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplingses_ES
TipoArtículoes_ES
ArbitradoHa sido Arbitradoes_ES
AutorRoberto Pioquinto-Mendoza, J.
AutorConelly-Espinosa, Patricia
AutorReyes-Martinez, Reyna
AutorToscano, Ruben A.
AutorGerman-Acacio, Juan M.
AutorAvila-Sorrosa, Alcives
AutorBaldovino-Pantaleon, Oscar
AutorMorales-Morales, David
AutorRoberto Pioquinto-Mendoza, J.es_ES
AutorConelly-Espinosa, Patriciaes_ES
AutorReyes-Martinez, Reynaes_ES
AutorToscano, Ruben A.es_ES
AutorGerman-Acacio, Juan M.es_ES
AutorAvila-Sorrosa, Alciveses_ES
AutorBaldovino-Pantaleon, Oscares_ES
AutorMorales-Morales, Davides_ES
InstituciónUniversidad Autónoma de Tamaulipas
InstituciónUniversidad Autónoma de Tamaulipases_ES
Rango de páginas153-158es_ES
URL relacionadahttps://doi.org/10.1016/j.jorganchem.2015.08.024
Tipo de artículoIndexado
Tipo de artículoIndexadoes_ES
Volumen797es_ES

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